She was elected to Rhondda Borough Council in 1992, Mid-Glamorgan County Council in 1993, and, following the abolition of these, to the Rhondda Cynon Taf Council in 1996. She was elected to the European Parliament at the 1999 elections, becoming the first Plaid Cymru MEP. Evans was re-elected at the 2004 elections, in June 2009 and again in the 2014 election. She stood for the Rhondda constituency in the National Assembly for Wales election, 2007 and came second with 6,660 votes (30.1%).