Vee was born and raised in the Los Angeles area, growing up in Norwalk. When she was younger she wanted to become an Animator, but after watching Sailor Moon, she was inspired to go into voice acting. She had attended Anime Expo multiple times as a fan, and participated in their AX Idol voice-over contest. In 2004, she joined a voice-over panel where she helped work some of the equipment and then got a card from Wendee Lee to audition for several shows with Bang Zoom! Entertainment, including Samurai Champloo. Her first major role was Kanaria in Rozen Maiden. She studied Theatre Arts and graduated from California State University at Long Beach in 2007. In 2008, she voiced the title character in Aika R-16: Virgin Mission, Louise in The Familiar of Zero and Nanoha in Magical Girl Lyrical Nanoha. She portrayed the live-action Haruhi Suzumiya in the promotional videos for the second The Melancholy of Haruhi Suzumiya series, and performed as her at various events.